کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1037125 943910 2009 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Method-dependent variations in stable isotope results for structural carbonate in bone bioapatite
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله
Method-dependent variations in stable isotope results for structural carbonate in bone bioapatite
چکیده انگلیسی

Stable carbon and oxygen isotope values (δ13C, δ18O) were obtained for structural carbonate in the bioapatite of archaeological bones from Guatemala and Sudan using several common analytical methods. For the Sudan samples, the different methods produced δ13C values within ±0.1‰ and δ18O values within ±0.7‰, on average. The isotopic results for the Guatemala samples were similar in reproducibility to the Sudan samples when obtained using methods that employed lower reaction temperatures and reactions in sealed vessels. However, many Guatemala samples had highly variable and extremely low δ18O values when reacted at higher temperatures in vessels that remained open to cryogenic traps. The latter arrangement caused reaction products to be removed immediately upon their production. The anomalously low δ18O values are related to the production of a contaminant gas that causes the m/z 46/44 ratio to be lowered, either by adding to the m/z 44 peak or subtracting from the m/z 46 peak. That said, potential contaminant materials were not detectable in “anomalous” bones using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction, or inductively-coupled plasma atomic emission spectroscopy. However, subtle structural and chemical differences between “normal” and “anomalous” samples were observed, most notably in the FTIR ν2 CO3 domain. We suggest that these changes promote volatilization of an oxyphosphorus compound and oxygen isotope fractionation between PO− derived from this compound and CO2 derived from bone carbonate. Production of the contaminant gas and the related “anomalous” δ18O values is reversible if the reaction occurs within a sealed vessel for a sufficient period of time, which allows a “back-reaction” to occur.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Archaeological Science - Volume 36, Issue 1, January 2009, Pages 110–121
نویسندگان
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