کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10372776 | 877824 | 2011 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Importance of carbon surface chemistry in development of iron-carbon composite adsorbents for arsenate removal
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
Micro/mesoporous activated carbon was oxidized and used either as received or after modification as a support for the deposition of iron oxyhydroxide. The prepared samples were applied as adsorbents of arsenate from water phase. The initial materials and those after adsorption were characterized using adsorption of nitrogen, - potentiometric titration, FTIR, EDX, XRD, AAS, and thermal analysis. The results obtained suggest that oxidation of the carbon support increases significantly the amount of iron oxyhydroxide species deposited on the surface and thus decreases their dispersions and the efficiency of arsenate immobilization in the carbon pore system. Iron hydroxyoxides react with arsenate forming salts. Moreover, a meso/microporous carbon surface contributes to changes in the toxicity of arsenic via reduction of As(V) to As(III). This is visible in the increased degree of carbon oxidation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 186, Issue 1, 15 February 2011, Pages 667-674
Journal: Journal of Hazardous Materials - Volume 186, Issue 1, 15 February 2011, Pages 667-674
نویسندگان
Eleni Deliyanni, Teresa J. Bandosz,