The controlled radical polymerisation process as an instrument for tailor-made coating applications

The last decade, polymer scientists have witnessed an avalanche of interest in extending the application potential of controlled radical polymerisation methods. The reason for this must be sought in the potential of these polymerisation techniques to allow the synthesis of polymers with unique characteristics. Herein, we present a general overview of the most used controlled radical polymerisation methods. Moreover, in the specific case of atom transfer radical polymerisation reactions (ATRP) a deeper insight in the process governing parameters/reagents is provided. After describing both the main characteristics of a controlled radical polymerisation process and the possibilities of these methods for synthesising new polymer structures, we conclude with a brief overview of the opportunities and challenges of controlled radical polymerisation methods in (textile) coating applications.