کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10428534 | 909219 | 2016 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Research on the g factors of Cr3+ ion in elpasolite crystals Cs2NaYX6 (XÂ =Â Cl, Br)
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
سایر رشته های مهندسی
مهندسی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The g factors of Cr3+ ions at the cubic octahedral Y3+ sites of elpasolite crystals Cs2NaYX6(X = Cl, Br) are computed from the high-order perturbation formula founded on the two-mechanism model. In the model, both the contribution from the crystal-field (CF) mechanism in the vastly-applied CF theory and that from the frequently-omitted charge-transfer (CT) mechanism are taken into account. The parameters used in the calculations are acquired from the first-principles calculations and experiment. The calculated results are in rational accordance with the observed values. The negative g-shift Îg (=g â ge, where ge â 2.0023, the g value of free electron) for Cs2NaYCl6:Cr3+ and the positive g-shift Îg for Cs2NaYBr6:Cr3+ are therefore explained. The reasonableness of the above calculated formula and the parameters used are confirmed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Optik - International Journal for Light and Electron Optics - Volume 127, Issue 18, September 2016, Pages 7088-7091
Journal: Optik - International Journal for Light and Electron Optics - Volume 127, Issue 18, September 2016, Pages 7088-7091
نویسندگان
Xiao-Xuan Wu, Wen-Chen Zheng,