کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10567497 | 973278 | 2011 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of copper doping on LiMnPO4 prepared via hydrothermal route
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Fine-sized, well-crystallized LiMnPO4 and two Cu-doped derivatives (2% and 5% Cu2+ doping) are readily prepared via a hydrothermal route. X-ray diffraction (XRD) combined with structural analysis, scanning electron microscopy (SEM), transmission electron microscopy (TEM), specific surface area analysis, and galvanostatic charge-discharge tests are applied to characterize these materials. The structure analysis shows that only a negligible amount of Cu2+ ions (0.2%) occupy the Li sites in the 2% Cu-doped material, while a considerable amount of Cu2+ ions (1.8%) occupy the Li sites in the 5% Cu-doped one. The electrochemical tests show that the 2% Cu-doped LiMnPO4 displays an improved electrochemical performance compared with the undoped LiMnPO4, while the 5% Cu-doped LiMnPO4 exhibits a decreased activity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 196, Issue 15, 1 August 2011, Pages 6498-6501
Journal: Journal of Power Sources - Volume 196, Issue 15, 1 August 2011, Pages 6498-6501
نویسندگان
Jiangfeng Ni, Lijun Gao,