کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10570116 | 974787 | 2005 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, spectroscopic characterization, X-ray crystal structure and magnetic properties of dinuclear copper(II) complex with dual end-to-end and end-on cyanate bridges: [Cu2(μ-NCO-N,Nâ²)2(NCO-N)2(dpyam)2]
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis, spectroscopic characterization, X-ray crystal structure and magnetic properties of dinuclear copper(II) complex with dual end-to-end and end-on cyanate bridges: [Cu2(μ-NCO-N,Nâ²)2(NCO-N)2(dpyam)2] Synthesis, spectroscopic characterization, X-ray crystal structure and magnetic properties of dinuclear copper(II) complex with dual end-to-end and end-on cyanate bridges: [Cu2(μ-NCO-N,Nâ²)2(NCO-N)2(dpyam)2]](/preview/png/10570116.png)
چکیده انگلیسی
A new dinuclear copper(II) complex [Cu2(μ1,1-NCO)2(NCO)2(dpyam)2] (dpyam = di-2-pyridylamine) has been synthesized and characterized by X-ray diffraction. Two N-bonded cyanato ligands bridge two copper ions in an end-on fashion and two others act as the N-bonded terminal ligands. The copper ion has a distorted square-pyramidal environment. The magnetic susceptibility, measured from 5 to 300 K, has revealed a weak ferromagnetic interaction between the Cu(II) atoms with a singlet-triplet energy gap (J) of 6.03 cmâ1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Inorganic Chemistry Communications - Volume 8, Issue 10, October 2005, Pages 882-885
Journal: Inorganic Chemistry Communications - Volume 8, Issue 10, October 2005, Pages 882-885
نویسندگان
Sujittra Youngme, Jaturong Phatchimkun, Unchulee Suksangpanya, Chaveng Pakawatchai, Gerard A. van Albada, Jan Reedijk,