کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10578639 | 979766 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of gadolinium(III) and samarium(III) complexes of new potentially heptadentate (N4O3) tripodal Schiff base ligands, and a theoretical study
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The synthesis and characterization of two new potentially heptadentate N4O3 tripodal Schiff base ligands H3L1 and H3L2 are reported. The neutral gadolinium(III) and samarium(III) complexes, [Ln(L)], of these bulky ligands and also a gadolinium(III) complex of a previously known ligand, H3L3, were also synthesized and characterized by various spectroscopic methods. The relative capability of these ligands as well as their unsubstituted analogs to encapsulate a lanthanide ion, herein La(III), has been theoretically studied.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Polyhedron - Volume 24, Issue 12, 25 August 2005, Pages 1478-1486
Journal: Polyhedron - Volume 24, Issue 12, 25 August 2005, Pages 1478-1486
نویسندگان
Sadegh Salehzadeh, Seyedeh Mahnaz Nouri, Hassan Keypour, Mojtaba Bagherzadeh,