کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10624251 989585 2016 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Facile obtainment of luminescent glass-ceramics by direct firing of a preceramic polymer and oxide fillers
ترجمه فارسی عنوان
بدست آوردن نمونه های شیشه ای سرامیکی از طریق شلیک مستقیم از پلیمرهای پرکریموم و پرکننده های اکسید
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
چکیده انگلیسی
Rare-earth (RE) doped glass-ceramics represent very interesting luminescent materials. The thermal annealing of the glass precursor causes the controlled precipitation of several crystalline phases, in which RE may be variously distributed, also with different oxidation states, e.g. Eu2+ and Eu3+. The present investigation demonstrates the feasibility of preparation of RE-doped alumino-boro-silicate glass-ceramics by direct firing in air (at 1000-1200 °C) of a preceramic polymer, filled with nano- and micro-sized particles, as an alternative to glass melting and annealing. In particular BaCO3 or SrCO3 micro-particles, mixed with nano-sized γ-Al2O3, were found to react with amorphous silica, available from the oxidative decomposition of a commercial silicone, yielding a strontium or a barium alumino-silicate phase. Boric acid micro-particles contributed both to the development of a liquid phase upon firing (promoting ionic interdiffusion) and to the formation of a La-borate phase, by interaction with La2O3 micro-particles. The blue and red luminescence of the obtained glass-ceramics is attributed to the incorporation of Eu2+ and Eu3+ ions, from nano-sized Eu2O3 filler, in alumino-silicate and borate phases, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 42, Issue 6, 1 May 2016, Pages 6770-6774
نویسندگان
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