کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10625549 989632 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Syntheses of bismuth titanate templates obtained by the molten salt method
ترجمه فارسی عنوان
سنتزهای قالب بیسموت تیتانات به دست آمده از روش نمک مذاب
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
چکیده انگلیسی
Bismuth titanate templates (Bi4Ti3O12) were synthesized by the molten salt method in Na2SO4 and K2SO4 fluxes, using an amorphous Bi4Ti3O12 precursor and a mechanically mixed Bi2O3+TiO2 mixture as the starting materials. The templates were characterized by means of X-Ray Diffraction, FT-IR, FT-Raman, FEG-SEM and TEM. The templates are free of secondary phases and present orthorhombic structure with orientation in the c-plane. FT-IR suggests no traces of sulfate groups revealing that the molten salt synthesis was beneficial for elimination of inorganic species and for the arrangement of individual nanocrystals into ordered lattices. FEG-SEM analyses of BIT templates revealed that most of the grains were homogeneous with a length of 3.1 µm and a width of 0.3 µm and had plate-like morphology. TEM investigations show that the c-axis of the perovskite units is parallel to the thickness direction of the grains and no liquid-phase was formed during BIT phase formation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 39, Issue 7, September 2013, Pages 7291-7296
نویسندگان
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