کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10625607 | 989632 | 2013 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dielectric properties of Bi-doped Ba0.8Sr0.2TiO3 ceramic solid solutions
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Bismuth-doped barium-strontium-titanate ceramics of the formula (Ba0.8Sr0.2)(1â1.5y)BiyTiO3 were prepared using a conventional solid-state reaction method. The structure, dielectric properties, and ferroelectric relaxor behaviour of all compositions were thoroughly investigated. The findings revealed a broad dielectric anomaly and a shift in dielectric maxima towards higher temperatures with increasing frequency. The diffuseness degree indicator γ was about 1.68, and dielectric relaxation was noted to follow the Vogel-Fulcher relationship, with Tf=185 K, f0=1.18Ã1010 Hz, and Ea=0.35 eV, which further supported the spin-glass-like properties of BBSTs. The latter were also noted to display significant ferroelectric relaxor behaviour that could be attributed to the presence of Bi3+ doping ions. The degree of relaxation behaviour was noted to increase with the increase in bismuth concentration. Raman spectra were investigated as a function of temperature, and the findings confirmed the results from X-ray and dielectric measurements. Among the compositions assayed in this solid solution, 10% Bi-doped Ba0.8Sr0.2TiO3 yielded promising relaxor properties that make it a strong candidate for future industrial application in the production of efficient and eco-friendly relaxor ferroelectric materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 39, Issue 7, September 2013, Pages 7571-7575
Journal: Ceramics International - Volume 39, Issue 7, September 2013, Pages 7571-7575
نویسندگان
Fathi Bahri, Hamadi Khemakhem,