کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10626319 | 989649 | 2011 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of PZT fine particles using Ti3+ precursor at a low hydrothermal temperature of 110 °C
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
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چکیده انگلیسی
Lead zirconate titanate (PZT) fine particles (80 nm to 0.8 μm) were prepared by hydrothermal method using a Ti3+ precursor, TiCl3. In contrast with conventional hydrothermal methods using Ti4+-reagents, pure PZT particles without lead titanate (PTO) impurities were synthesized using the Ti3+-reagent at a low temperature of 110 °C which is lower than the previously reported temperatures of 160 and 130 °C, using Ti4+-reagents of TiO2 and TiCl4, respectively. Additionally, the crystallization time using the Ti3+-reagent is shorter than those using Ti4+-reagents at the same temperature of 140 °C. The high reaction rate of the Ti3+-reagent containing gels prepared here is probably due to the presence of much more defects in their PTO intermediates. The present hydrothermal method using Ti3+ precursor could lead to energy savings because of low temperature synthesis and the present method is potentially useful for non-pressurized equipment in manufacturing plants for synthesizing PZT particles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 37, Issue 3, April 2011, Pages 1101-1107
Journal: Ceramics International - Volume 37, Issue 3, April 2011, Pages 1101-1107
نویسندگان
Seok Han Kim, Sridhar Komarneni,