کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10626677 | 989696 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of Li1âxNi1+xO2 using malonic acid as a chelating agent
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Li1âxNi1+xO2 powder was synthesized by polymerised complex method using malonic acid as a chelating agent. The carboxylate precursor was calcined in the temperature range 650-800 °C for 14-48 h. The TG curves of malonic acid, lithium acetate dihydrate, nickel acetate tetrahydrate and the precursor were studied at 29.52-600 °C. The FTIR spectra of the precursor without and with 650-800 °C calcination were used to explain the vibrational bonding. At 750 °C and above, only Li1âxNi1+xO2 phase was detected. The maximum [I(003)/I(104)] and minimum [I(006+102)/I(101)] intensity ratios of the XRD spectra were used to determine the optimum temperature and time of calcination for preparation of Li1âxNi1+xO2 powder. In addition, formation mechanism of Li1âxNi1+xO2 is proposed. The content of nickel, lithium, Ni3+/(Ni3+ + Ni2+) and mean oxidation state of nickel at 650-800 °C were determined and they show very good agreement. The SEM micrograph is also used to explain the morphology of the powder.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 31, Issue 2, 2005, Pages 241-247
Journal: Ceramics International - Volume 31, Issue 2, 2005, Pages 241-247
نویسندگان
Titipun Thongtem, Somchai Thongtem,