کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10629696 991139 2012 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Dense bulk silicon oxycarbide glasses obtained by spark plasma sintering
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Dense bulk silicon oxycarbide glasses obtained by spark plasma sintering
چکیده انگلیسی
Dense silicon oxycarbide glasses (SiOC) have been produced by spark plasma sintering (SPS) of SiOC powders. Raw powders were obtained by pyrolysis under nitrogen at 1100 °C of tetraethylorthosilcate/polydimethylsiloxane (TEOS/PDMS) hybrids. SPS experiments were carried out at 1300 and 1500 °C at 10 and 80 MPa and then were studied by chemical analysis, 29Si and 13C MAS NMR, ATR, Raman, XRD, FE-SEM, density, porosity, microhardness (Hv) and thermal conductivity (K). The SiOC materials are formed by SixOC4−x units within a silica matrix where silicon carbide and graphite nanodomains are also present. After the SPS treatment the silicon carbide crystallite size is close to 2.5 nm. At 1300 °C and 1500 °C the carbon nanodomain size is close to 3 nm and 2 nm, respectively. Hv values vary from 3.4 to 9.15 GPa, for 30% and 1% of porosity, respectively. Finally, K is always close to 1.38 W m−1 K−1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the European Ceramic Society - Volume 32, Issue 12, September 2012, Pages 3369-3378
نویسندگان
, , , , , ,