کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10629863 | 991194 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Oxygen ionic transport in SrFe1âyAlyO3âδ and Sr1âxCaxFe0.5Al0.5O3âδ ceramics
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The oxygen permeability of mixed-conducting Sr1âxCaxFe1âyAlyO3âδ (x=0-1.0; y=0.3-0.5) ceramics at 850-1000 °C, with an apparent activation energy of 120-206 kJ/mol, is mainly limited by the bulk ionic conduction. When the membrane thickness is 1.0 mm, the oxygen permeation fluxes under pO2 gradient of 0.21/0.021 atm vary from 3.7Ã10â10 mol sâ1 cmâ2 to 1.5Ã10â7 mol sâ1 cmâ2 at 950 °C. The maximum solubility of Al3+ cations in the perovskite lattice of SrFe1âyAlyO3âδ is approximately 40%, whilst the brownmillerite-type solid solution formation range in Sr1âxCaxFe0.5Al0.5O3âδ system corresponds to x>0.75. The oxygen ionic conductivity of SrFeO3-based perovskites decreases moderately on Al doping, but is 100-300 times higher than that of brownmillerites derived from CaFe0.5Al0.5O2.5+δ. Temperature-activated character and relatively low values of hole mobility in SrFe0.7Al0.3O3âδ, estimated from the total conductivity and Seebeck coefficient data, suggest a small-polaron mechanism of p-type electronic conduction under oxidising conditions. Reducing oxygen partial pressure results in increasing ionic conductivity and in the transition from dominant p- to n-type electronic transport, followed by decomposition. The low-pO2 stability limits of Sr1âxCaxFe1âyAlyO3âδ seem essentially independent of composition, varying between that of LaFeO3âδ and the Fe/Fe1âγO boundary. Thermal expansion coefficients of Sr1âxCaxFe1âyAlyO3âδ ceramics in air are 9Ã10â6 Kâ1 to 16Ã10â6 Kâ1 at 100-650 °C and 12Ã10â6 Kâ1 to 24Ã10â6 Kâ1 at 650-950 °C. Doping of SrFe1âyAlyO3âδ with aluminum decreases thermal expansion due to decreasing oxygen nonstoichiometry variations.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the European Ceramic Society - Volume 25, Issue 4, April 2005, Pages 489-499
Journal: Journal of the European Ceramic Society - Volume 25, Issue 4, April 2005, Pages 489-499
نویسندگان
A.L. Shaula, V.V. Kharton, N.P. Vyshatko, E.V. Tsipis, M.V. Patrakeev, F.M.B. Marques, J.R. Frade,