کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10638320 | 995415 | 2005 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Luminescent and photocatalytic properties of cadmium sulfide nanoparticles synthesized via microwave irradiation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Uniform cadmium sulfide (CdS) nanoparticles of about 6 nm in crystal size have been successfully synthesized via microwave irradiation. The as-prepared sample has a uniform morphology and high purity. The red photoluminescence spectrum of the CdS nanoparticles displays a strong peak at 602 nm by using a 300 nm excitation wavelength. The photocatalytic oxidation of methyl orange (MeO) in CdS suspensions under ultraviolet illumination was investigated. The results indicate that a low pH value (pH 2.0) and low reaction temperatures (20-30 °C) will facilitate the decolorization of the MeO solution. The photodegradation degree decreases with increasing the pH value and temperature of solution. The efficiency of the recycled CdS semiconductor becomes lower due to the deposit of elemental Cd on the CdS surface, which weakens the photocatalytic activity. The luminescent and photocatalytic mechanisms of the as-prepared CdS nanoparticles were primarily discussed. Microwave irradiation is proved to be a convenient, efficient and environmental-friendly one-step route to synthesize nanoparticles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 90, Issue 1, 15 March 2005, Pages 155-158
Journal: Materials Chemistry and Physics - Volume 90, Issue 1, 15 March 2005, Pages 155-158
نویسندگان
Huaming Yang, Chenghuan Huang, Xianwei Li, Rongrong Shi, Ke Zhang,