کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10666508 | 1007726 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and structural analyses of poly (1, 2-cyclohexene oxide) over solid acid catalyst
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The polymerization of 1, 2-cyclohexene oxide was carried out at 20 °C in dichloromethane with an acid-exchanged montmorillonite as acid solid catalyst. The effect of the amount of catalyst, solvent, and temperature was studied. A typical reaction product (PCHO) was analyzed by infrared and nuclear magnetic resonance spectroscopy, as well as by gel-permeation chromatography and MALDI-TOF MS, X-ray diffraction, and differential scanning calorimetry (DSC). The X-ray and DSC data show that PCHO is an amorphous substance. The mechanism of the polymerization appears to be cationic.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 59, Issue 7, March 2005, Pages 759-767
Journal: Materials Letters - Volume 59, Issue 7, March 2005, Pages 759-767
نویسندگان
Ahmed Yahiaoui, Mohammed Belbachir, Jeanne Claude Soutif, Laurent Fontaine,