کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10682824 | 1016165 | 2010 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and characterization of anhydrous proton conducting inorganic-organic composite membranes for medium temperature proton exchange membrane fuel cells (PEMFCs)
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی (عمومی)
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چکیده انگلیسی
We report on anhydrous proton conducting inorganic-organic composite membranes synthesized from tetraethoxysilane/poly(-dimethylsiloxane)/trimethylphosphate and 1-ethyl-3 methylimidazolium-bis (trifluoromethanesulfonyl) imide ionic liquid as sol-gel precursors. The Fourier transform infrared spectroscopy, 31P, 1H, and 13C Nuclear magnetic resonance, thermo gravimetric and differential thermal analysis measurements confirmed that the prepared hybrid membranes possess good chemical stability and are thermally stable up to 350 °C. Conductivity of all the fabricated hybrid membranes was measured under anhydrous conditions within the temperature range â20-150 °C, and a value of 4.87 Ã 10â3 S/cm at 150 °C was achieved for 40 wt% [EMI][TFSI] ionic liquid doped 72TEOS-18PDMS-10PO (OCH3)3 (mol %) hybrid membrane. For 40 wt% ionic liquid doped composite membrane, the measured hydrogen permeability value at 150 °C was 4 Ã 10â12 mol/cm s Pa.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Energy - Volume 35, Issue 12, December 2010, Pages 5260-5268
Journal: Energy - Volume 35, Issue 12, December 2010, Pages 5260-5268
نویسندگان
G. Lakshminarayana, Masayuki Nogami, I.V. Kityk,