کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
11012852 1797861 2018 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Co(III)/Zn(II)-catalyzed dearomatization of indoles and coupling with carbenes from ene-yne ketones via intramolecular cyclopropanation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Co(III)/Zn(II)-catalyzed dearomatization of indoles and coupling with carbenes from ene-yne ketones via intramolecular cyclopropanation
چکیده انگلیسی
A straightforward and efficient protocol for dearomatizing indoles is described. The reaction, catalyzed by an inexpensive Co(III)/Zn(II) catalyst, starts from conveniently accessible N-pyrimidinyl indoles and ene-yne ketones. Mild reaction conditions, high diastereoselectivity, a broad substrate scope, reasonable functional group tolerance, and reasonable to remarkable yields were observed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Journal of Catalysis - Volume 39, Issue 12, December 2018, Pages 1881-1889
نویسندگان
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