کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
11019831 1717621 2019 42 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Energy intensified integrated advanced oxidation technology for the treatment of recalcitrant industrial wastewater
ترجمه فارسی عنوان
انرژی تشدید یک تکنولوژی پیشرفته اکسیداسیون برای درمان فاضلاب صنعتی بازدارنده
موضوعات مرتبط
مهندسی و علوم پایه مهندسی انرژی انرژی های تجدید پذیر، توسعه پایدار و محیط زیست
چکیده انگلیسی
This work aimed at providing additional information and knowledge on the possibility to overcome the limitation of conventional advanced oxidation processes (AOPs) through hybridization. In the present work, a number of photochemical and non-photochemical AOPs such as direct photolysis (UV), photolysis of hydrogen peroxide using UV light (UV/H2O2), UV assisted coagulation (UV Fe2+ coagulation), Fenton process, Fe2+ coagulation and photo-Fenton process were compared to determine their feasibility to treat real textile wastewater. The Batik industry, which is a textile cottage industry in Malaysia has reported problems related to safe environmental disposal of its pollutants, mainly dyestuff. The comparison was made in terms of Chemical oxygen demand (COD), Total organic carbon (TOC) and colour removal together with electricity consumption. Among the processes evaluated, the highest COD removal was achieved for photo -Fenton oxidation (91.2%), followed by Fenton oxidation (81.4%), UV/H2O2 (68.0%), UV- Fe2+ coagulation (55.0%), Fe2+ coagulation (43.0%) and UV photolysis (10.0%). At the optimal operating conditions (room temperature, undiluted contaminants), the photo-Fenton hybrid process achieved complete decolourization and higher removal of COD (91.2%) and TOC (78.5%) with minimum electrical energy per order of 0.02 kWhr/m3 compared to other AOPs. About 13% reduction in the total chemical cost and 10% increase in the degradation were observed by combining the Fenton process with UV radiation compared to the conventional Fenton process. The GC/MS analysis revealed that the photo-Fenton process successfully removed 87% of organic compounds. The sludge characterization studies by Particle Size Distribution proved that the Fenton-generated sludge achieved quality suitable for disposal. Photo-Fenton is the cheapest option with highest removal (91%) as its required only $0.0016 to degrade 1 g of COD compared to Fenton which cost $0.0021. Therefore, this study concluded that the photo-Fenton process was an economically viable and appropriate treatment method for enhancing biodegradability of recalcitrant contaminants.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Cleaner Production - Volume 206, 1 January 2019, Pages 1025-1040
نویسندگان
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