کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1228306 | 968457 | 2008 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: A membrane introduction flame ionization/electron capture detection (MIFID/ECD) system for the rapid, real-time screening of volatile disinfection byproducts and hydrocarbon contaminants in water A membrane introduction flame ionization/electron capture detection (MIFID/ECD) system for the rapid, real-time screening of volatile disinfection byproducts and hydrocarbon contaminants in water](/preview/png/1228306.png)
Described is a system that employs an online membrane introduction (MI) interface coupled with parallel flame ionization and electron capture detectors (FID/ECD). We report the use of a MIFID/ECD system as an online method to detect total volatile organic halides (ΣVOXs) and volatile organic compounds (ΣVOCs) as aggregate parameters in environmental water samples at sub parts-per-billion levels without the need for sample handling or analyte pre-concentration. The instrument provides rapid screening and real-time monitoring capabilities of important classes of water contaminants in a simple system without the vacuum requirements of MS detectors. Furthermore, the MIFID/ECD instrument was successfully employed as a real-time reaction monitor for the photodegradation of toluene by an advanced oxidation process and the formation of volatile disinfection byproducts in the chlorination of natural waters. The results of these experiments compare favorably to those obtained using membrane introduction mass spectrometry (MIMS).
Journal: Microchemical Journal - Volume 88, Issue 1, February 2008, Pages 74–81