کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1229331 | 1495212 | 2016 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: A new rhodamine-based colorimetric chemosensor for naked-eye detection of Cu2 + in aqueous solution A new rhodamine-based colorimetric chemosensor for naked-eye detection of Cu2 + in aqueous solution](/preview/png/1229331.png)
• The rhodamine-based sensor is simple to synthesize. Its structure was confirmed by single crystal X-ray diffraction.
• This sensor can be used to determine Cu2 + ion with high selectivity and sensitivity.
• The recognition of Cu2 + gave rise to color changes from colorless to pink that was clearly visible to the naked eye.
A new colorimetric probe 1 based on rhodamine B lactam was developed for naked-eye detection of Cu2 +. The optical feature of 1 for Cu2 + was investigated by UV–vis absorption spectroscopy. Upon the addition of Cu2 +, the 1 displayed a distinct color change from colorless to pink, which can be directly detected by the naked eye. The stoichiometry of 1 to Cu2 + complex was found to be 1:1 and the naked-eye detection limit was determined as low as 2 μM. The results suggest that the probe 1 may provide a convenient method for visual detection of Cu2 + with high sensitivity.
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Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 157, 15 March 2016, Pages 164–169