کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1230520 | 1495247 | 2014 | 8 صفحه PDF | دانلود رایگان |
• We designed and synthesized N-acetylglyoxylic amide-based colorimetric anion sensors.
• Sensors 4 and 5 showed obvious color changes upon addition of CN− and F−.
• CN− and F− formed hydrogen bonds with the receptors and induced subsequent deprotonation.
N-acetylglyoxylic amides 4 and 5 bearing pendant 4-nitrophenyl and 2,4-dinitrophenyl groups respectively were synthesized and evaluated as anion sensors. A crystal structure of 4 was obtained by X-ray crystallography. Compounds 4 and 5 behaved as colorimetric sensors for CN− and F−, and exhibited naked eye-detectable color changes upon the addition of these anions. The chromogenic properties of 4 and 5 were assessed by UV–Vis and 1H NMR spectroscopy.
N-acetylglyoxylic amides based anion colorimetric sensors 4 and 5 demonstrated recognition of CN− and F−via hydrogen bonds and subsequent NH deprotonation which led to the intramolecular charge-transfer resulting in visible color changes.Figure optionsDownload as PowerPoint slide
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 121, 5 March 2014, Pages 662–669