کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1231296 | 1495254 | 2013 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Dynamic quenching study of 2-amino-3-bromo-1,4-naphthoquinone by titanium dioxide nano particles in solution (methanol) Dynamic quenching study of 2-amino-3-bromo-1,4-naphthoquinone by titanium dioxide nano particles in solution (methanol)](/preview/png/1231296.png)
• Aromatic amines are known to act as strong electron donors.
• Stern–Volmer plot indicates the dynamic nature of quenching process.
• Mechanism of electron transfer between ABNQ and TiO2 is responsible for the features.
The dependence of fluorescence emission of 2-amino-3-bromo-1,4-naphthoquinone on titanium dioxide (TiO2) in methanol has been investigated. The increase in TiO2 concentration causes a decrease in the fluorescence intensity of 2-amino-3-bromo-1,4-naphthoquinone. A linear Stern–Volmer plot in this study indicates the presence of dynamic quenching. The quenching and association constants have been calculated. The quenching process is due to the electron transfer from 2-amino-3-bromo-1,4-naphthoquinone to TiO2.
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Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 114, October 2013, Pages 272–276