کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1232615 | 1495282 | 2012 | 5 صفحه PDF | دانلود رایگان |
A dual mode chemosensor dye 3 for detection of fluoride ion, based on the D–π–A molecular framework by one-step condensation, presents high selectivity and sensitivity both in colorimetric and fluorometric analyses. Upon the addition of F− anion, the absorption band shows a remarkable red shift along with fluorescent intensity decreasing. The absorption and fluorescent intensities of the dye 3 can be reversibly selected by deprotonation/protonation of the amine moiety via control of intramolecular charge transfer (ICT), leading to a molecular switch with “on” and “off” states. 1H NMR titration analysis and DMol3 calculation were employed to reveal the intermolecular charge transfer system of dye 3–F− complex.
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► The F− selective dye 3 based on D–π–A framework is synthesized.
► Colorimetric and fluorometric analyses of dye 3 upon addition of F− are described.
► F− ions can interact with dye 3 forming anion–dye adducts.
► The pH stimuli-responsive property of dye 3 is determined.
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 86, February 2012, Pages 294–298