کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1233317 | 968806 | 2011 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and vibrational spectroscopic analysis of some Hofmann type clathrates
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and vibrational spectroscopic analysis of some Hofmann type clathrates Synthesis and vibrational spectroscopic analysis of some Hofmann type clathrates](/preview/png/1233317.png)
چکیده انگلیسی
New Hofmann type clathrates in the form of M(pp)2Ni(CN)4·2G (where pp = 1-phenylpiperazine, G = 1,4-dioxane and M = Ni, Co or Cd) have been prepared in powder form and their FT-IR and FT-Raman spectra are reported. The results suggest that the present compounds are similar in structure to the Hofmann type clathrates and their structures consist of conjugated polymeric layers of |M–Ni(CN)4|∞ with the pp bound to the metal (M) atom.
Figure optionsDownload as PowerPoint slideHighlights
► Vibrational investigation of Hofmann type clathrates.
► Using a non-aromatic guest molecule as 1,4-dioxane.
► The host–guest interactions are weak.
► The trapped 1,4-dioxane guest molecules have kept their free forms.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 82, Issue 1, November 2011, Pages 383–388
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 82, Issue 1, November 2011, Pages 383–388
نویسندگان
Cemal Parlak, Mustafa Şenyel,