کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1234031 | 968821 | 2010 | 9 صفحه PDF | دانلود رایگان |
The present paper reports the synthesis of a designed bisporphyrin (1), and its supramolecular complexes with C60 and C70 in toluene medium. Ground state non-covalent interaction between fullerenes and 1 is evidenced from absorption spectrophotometric study in which it is observed that the intensity of the Soret absorption band of 1 decreases considerably in presence of both C60 and C70. Jobs plot of continuous variation method establishes 1:1 stoichiometry for fullerene/1 complexes. Steady state fluorescence studies reveal efficient quenching of fluorescence of 1 in presence of fullerenes. The Stern–Volmer diffusion constant for the supramolecular complexes of 1 with C60 and C70 is determined to be 1450 and 12,485 dm3 mol−1. The binding constants of the C60/1 and C70/1 complexes are estimated to be 12,500 and 17,200 dm3 mol−1, respectively. Time-resolved emission studies establish relatively long-lived charge separated state for the C70/1 complex. Transient absorption spectral analysis reveals formation of radical anion species, i.e., C60− and C70− Molecular mechanics calculations at force field model in vacuo evoke the stereoscopic structures of the fullerene/1 complexes and interpret the stability difference between C60 and C70 complexes of 1 in terms of heat of formation values.
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 77, Issue 1, 15 September 2010, Pages 64–72