کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1234317 1495244 2014 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Exploratory studies towards various anion recognition chemistry by two different sized cleft shaped organic ligands
ترجمه فارسی عنوان
مطالعات اکتشافی نسبت به شیمی مختلف تشخیص آنیون توسط دو لیگاند آلی شکل شکاف به شکل متفاوت است
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
چکیده انگلیسی


• We report cost effective luminescent as well as electrochemical chemosensors.
• The sensors can be made following a simple synthetic route.
• Shape and size selectivity of chemosensors are modelled for biologically important anions (F−, OAc− and H2PO4-).
• The sensing interactions are well explained by convenient spectrophotometric and electrochemical techniques.
• The receptors have improved binding abilities.

Indole and urea based two organic receptors have been synthesized by an easy synthetic process. These two receptors have strong sensitivity and selectivity for several bio-relevant anions. Receptor 1 and 2 were synthesized from indole-2-carboxylic acid and p-anisidine respectively, which are low cost starting materials. Receptor 1 can selectively sense anions like F−, OAc− and H2PO4-, while receptor 2 can only sense F− and H2PO4-. Both receptors are silent toward anions like Cl−, Br−, I− and NO3-. It is the difference in their shape and size which are responsible for different anion sensing. The nature of these host–guest type interactions was analyzed by convenient spectrophotometric techniques like UV–Vis, fluorescence, 1H NMR, FT-IR studies and also confirmed by electrochemical techniques like cyclic voltammetry studies of the two ligand receptors with convenient anions. Between receptor 1 and 2, receptor 2 was crystallographically characterized also.

Exploratory studies towards various anion recognition chemistry by two different sized cleft shaped organic ligandsFigure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 124, 24 April 2014, Pages 492–499
نویسندگان
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