Solid state “self-calibrated” EPR-dosimeters—advantageous and shortcomings

EPR dosimetry method with α-alanine as radiation sensitive material (RSM) is widely used in high dose dosimetry laboratories. However, it is not suitable for routine industrial applications mainly because of difficult EPR measurement procedure.In order to simplify quantitative EPR dosimetry measurements Yordanov and Gancheva developed so-called “self-calibrated” (sc) dosimeters consists of RSM (α-alanine, sugar, other ones), Mn2+/MgO as internal EPR intensity standard (IES) and a binder. The aim of this work was to check dosimetric properties of two experimental batches of sc EPR dosimeters with α-alanine and sugar as RSM, Mn2+/MgO as IES and paraffin as a binder. The percentage content of the components was 60, 5 and 35% (w/w), respectively.It was established that the investigated alanine sc-dosimeters are about two times more sensitive than the sugar ones. The dose–response coefficient, Kdr of sc-alanine dosimeters was stable in all investigated dose range from 1 to 23 kGy. The Kdr-value of sugar sc-dosimeters decreased with the dose what was in a contradiction to the results pointed to the high stability of radiation generated sugar radicals. The observed effect arose probably from the special chemical procedure used for the sc-sugar dosimeters production.The results confirmed an expectation that the position of sc dosimeter in the cavity is not important factor for accurate dose evaluation. It allows to read-out dosimetric signals in shorter time, with lower uncertainty and on less sophisticate EPR-spectrometers than that commonly used till now.The main shortcomings of sc dosimeters are: (a) the limitation of RSM suitable for sc dosimeters to these ones having strictly linear signal to dose characteristic; (b) necessity to assure very good homogeneity of dosimeter material; and (c) the cost of IES present in the amount of some percent in each sc dosimeter.