کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1236106 | 968861 | 2007 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Solvation of cobalt(II) and trifluoromethanesulfonate ions in N,N-dimethylformamide–methanol mixed solvent studied by means of FT-IR spectroscopy
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Solvation of cobalt(II) and trifluoromethanesulfonate ions in N,N-dimethylformamide–methanol mixed solvent studied by means of FT-IR spectroscopy Solvation of cobalt(II) and trifluoromethanesulfonate ions in N,N-dimethylformamide–methanol mixed solvent studied by means of FT-IR spectroscopy](/preview/png/1236106.png)
چکیده انگلیسی
FT-IR spectra of Co(CF3SO3)2–N,N-dimethylformamide (DMF)–methanol (MeOH) solutions have been measured over the whole range of solvent composition. The data together with the obtained previously spectra of DMF–MeOH mixtures have been analyzed using the difference spectra method in the region of CO and OH stretching bands. The number of DMF and MeOH molecules in the first solvation sphere of Co(II) ion versus solvent composition has been determined. The second solvation sphere has been revealed and characterized quantitatively. Solvation of trifluoromethanesulfonate (triflate) ion as well as ion association in DMF solution have been also studied.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 66, Issue 1, January 2007, Pages 1–8
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 66, Issue 1, January 2007, Pages 1–8
نویسندگان
Ewa Kamieńska-Piotrowicz, Janusz Stangret, Joanna Szymańska-Cybulska,