کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1236424 | 968869 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Excited state solvatochromic and prototropic behaviour of 4-aminodiphenylamine and 4,4′-diaminodiphenylamine—A comparative study by electronic spectra
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Excited state solvatochromic and prototropic behaviour of 4-aminodiphenylamine and 4,4′-diaminodiphenylamine—A comparative study by electronic spectra Excited state solvatochromic and prototropic behaviour of 4-aminodiphenylamine and 4,4′-diaminodiphenylamine—A comparative study by electronic spectra](/preview/png/1236424.png)
چکیده انگلیسی
Solvatochromic and prototropic behaviour of 4-aminodiphenylamine (4ADA) and 4,4′-diaminodiphenylamine (DADA) have been investigated in the solvents of different polarity and at various acid–base concentrations in the ground and excited states using absorption and fluorescence spectra. Solvatochromic shifts have been analysed and observed shifts are explained by the hydrogen bonding interactions. The prototropic study reveals that (i) absorption maximum of monocation of DADA is red shifted to its neutral form, and (ii) the fluorescence of 4ADA is red shifted on protonation. The abnormal fluorescence of 4ADA+ is found to be due to large solvent relaxation in polar medium.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 64, Issue 3, June 2006, Pages 631–636
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 64, Issue 3, June 2006, Pages 631–636
نویسندگان
S. Kothai Nayaki, M. Swaminathan,