کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1237586 | 968900 | 2009 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Studies on the interaction between benzidine and hemocyanin from Chinese mitten crab Eriocheir japonica sinensis (Decapoda, Grapsidae)
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Studies on the interaction between benzidine and hemocyanin from Chinese mitten crab Eriocheir japonica sinensis (Decapoda, Grapsidae) Studies on the interaction between benzidine and hemocyanin from Chinese mitten crab Eriocheir japonica sinensis (Decapoda, Grapsidae)](/preview/png/1237586.png)
چکیده انگلیسی
The interaction of benzidine (BZ) with hemocyanin (Hc) from Chinese mitten crab (Eriocheir japonica sinensis) was studied by fluorescence spectrum. BZ can quench the fluorescence of Hc by forming a new complex. The process of binding BZ on Hc was a spontaneous molecular interaction procedure. The thermodynamic parameters, the enthalpy change and entropy change were estimated to be 47.36Â kJÂ molâ1, 248.51Â JÂ molâ1Â Kâ1 according to the van' Hoff equation. This indicates that hydrophobic interaction played a major role in stabilizing the complex. The results of synchronous fluorescence spectroscopy and three-dimensional fluorescence spectra indicated that the structure of these tyrosine residues environments was altered by BZ, which could enter into the hydrophobic pocked of Hc.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 73, Issue 4, 15 August 2009, Pages 676-681
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 73, Issue 4, 15 August 2009, Pages 676-681
نویسندگان
Bo-Ping Tang, Yan-Qing Wang, Dai-Zhen Zhang,