کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1237853 | 968909 | 2009 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nickel(II) and copper(II) complexes with Schiff base ligand 2,6-diacetylpyridine bis(carbohydrazone): Synthesis and IR, mass, 1H NMR, electronic and EPR spectral studies
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Nickel(II) and copper(II) complexes with Schiff base ligand 2,6-diacetylpyridine bis(carbohydrazone): Synthesis and IR, mass, 1H NMR, electronic and EPR spectral studies Nickel(II) and copper(II) complexes with Schiff base ligand 2,6-diacetylpyridine bis(carbohydrazone): Synthesis and IR, mass, 1H NMR, electronic and EPR spectral studies](/preview/png/1237853.png)
چکیده انگلیسی
Nickel(II) and copper(II) complexes with general formula [M(H3DAPC)X] and [M(H2DAPC)H2O], where M = Ni(II) and Cu(II), X = NO3−, Cl− and CH3COO−, and DAPC = 2,6-diacetylpyridine-bis(carbohydrazone), have been synthesized and structurally characterized by elemental analyses, molar conductance measurements, magnetic susceptibility measurements and spectral techniques like IR, UV and EPR. The nickel(II) and copper(II) complexes are octahedral and tetragonal coordination geometries, respectively. The EPR spectra of copper complexes in powdered form show a broad signal with g values in order g|| > g⊥ > 2.0023. The value of covalency factor β and orbital reduction factor k accounts for the covalent nature of the complexes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 72, Issue 4, May 2009, Pages 851–857
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 72, Issue 4, May 2009, Pages 851–857
نویسندگان
Sulekh Chandra, Amit Kumar Sharma,