کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1238258 968928 2006 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Polarised IR-microscope spectra of guanidinium hydrogensulphate single crystal
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Polarised IR-microscope spectra of guanidinium hydrogensulphate single crystal
چکیده انگلیسی
Polarised IR-microscope spectra of C(NH2)3*HSO4 small single crystal samples were measured at room temperature. The spectra are discussed on the basis of oriented gas model approximation and group theory. The stretching νOH vibration of the hydrogen bond with the O⋯O distance of 2.603 Å gives characteristic broad AB-type absorption in the IR spectra. The changes of intensity of the AB bands in function of polariser angle are described. Detailed assignments for bands derived from stretching and bending modes of sulphate anions and guanidinium cations were performed. The observed intensities of these bands in polarised infrared spectra were correlated with theoretical calculation of directional cosines of selected transition dipole moments for investigated crystal. The vibrational studies seem to be helpful in understanding of physical and chemical properties of described compound and also in design of new complexes with exactly defined behaviors.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 64, Issue 4, July 2006, Pages 867-879
نویسندگان
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