کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1238365 1495286 2007 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Theoretical study of EPR spectra for Mn2+ ion in [Mg(H2O)6]SnCl6 single crystal
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Theoretical study of EPR spectra for Mn2+ ion in [Mg(H2O)6]SnCl6 single crystal
چکیده انگلیسی

The relationship between the impurity structures and the electron paramagnetic resonance (EPR) parameters D, (a–F) have been studied by diagonalizing the complete energy matrices for Mn2+ ion in [Mg(H2O)6]SnCl6 single crystal in a trigonal ligand field within a weak-field-representation. It is shown that the local lattice structure around Mn2+ ion in [Mg(H2O)6]SnCl6 exhibits an elongation distortion which is different at 290 K and 77 K. The local structure parameters R = 2.223 ± 0.027 Å, θ = 52.966 ± 0.004° and R = 2.205 ± 0.030 Å, θ = 53.155 ± 0.047° for Mn2+ ion in [Mg(H2O)6]SnCl6 are determined at different temperatures 290 K and 77 K, respectively, and EPR parameters D and (a–F) can also get a satisfactory explanation simultaneously.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 67, Issues 3–4, July 2007, Pages 890–893
نویسندگان
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