کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1238365 | 1495286 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Theoretical study of EPR spectra for Mn2+ ion in [Mg(H2O)6]SnCl6 single crystal
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Theoretical study of EPR spectra for Mn2+ ion in [Mg(H2O)6]SnCl6 single crystal Theoretical study of EPR spectra for Mn2+ ion in [Mg(H2O)6]SnCl6 single crystal](/preview/png/1238365.png)
چکیده انگلیسی
The relationship between the impurity structures and the electron paramagnetic resonance (EPR) parameters D, (a–F) have been studied by diagonalizing the complete energy matrices for Mn2+ ion in [Mg(H2O)6]SnCl6 single crystal in a trigonal ligand field within a weak-field-representation. It is shown that the local lattice structure around Mn2+ ion in [Mg(H2O)6]SnCl6 exhibits an elongation distortion which is different at 290 K and 77 K. The local structure parameters R = 2.223 ± 0.027 Å, θ = 52.966 ± 0.004° and R = 2.205 ± 0.030 Å, θ = 53.155 ± 0.047° for Mn2+ ion in [Mg(H2O)6]SnCl6 are determined at different temperatures 290 K and 77 K, respectively, and EPR parameters D and (a–F) can also get a satisfactory explanation simultaneously.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 67, Issues 3–4, July 2007, Pages 890–893
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 67, Issues 3–4, July 2007, Pages 890–893
نویسندگان
Ai-Jie Mao, Xiao-Yu Kuang, Xiao-Ming Tan, Hui Wang, Ju-Fen Li,