کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1254246 | 971359 | 2014 | 5 صفحه PDF | دانلود رایگان |
The present study reports a sensitive electro-analytical method for the simultaneous determination of dihydroxybenzene isomers by using a thiadiazole film electrode, which was readily prepared by electropolymerization of 2,5-dimercapto-1,3,4-thiadiazole on a glassy carbon electrode with cyclic voltammetry. The functionalized electrode has a distinguishable and sensitive response to dihydroxybenzene isomers. Under the optimized conditions, the linear stripping peak currents showed good linear relationships with hydroquinone, catechol and resorcinol at concentration ranges 0.50–120, 0.50–110 and 1.00–110 μmol/L, and the detection limits are 0.1, 0.1 and 0.3 μmol/L, respectively. The proposed method is applicable to the simultaneous determination of dihydroxybenzene isomers in real samples with the relative standard deviations of less than 5.7% and the recovery rates of 95.6%–106%. The constructed electrode is characterized by simple preparation, good selectivity, and high sensitivity advantages.
Dihydroxybenzene isomers were simultaneously determined utilizing a thiadiazole film electrode.Figure optionsDownload as PowerPoint slide
Journal: Chinese Chemical Letters - Volume 25, Issue 2, February 2014, Pages 370–374