کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1254296 971368 2016 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Two novel rhodamine-perylenediimide fluorescent probes: Synthesis, photophysical properties, and cell imaging
ترجمه فارسی عنوان
دو پرونده فلورسنت رودامین-پریلندیاییمید جدید: سنتز، خواص فتوفیزیکی و تصویربرداری سلول
کلمات کلیدی
پریلندیمید، رودامین، انتقال الکترون الکترونیک، سوئیچ دوگانه
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
چکیده انگلیسی

In this study, two novel dual-switch fluorescent chemosensors based on rhodamine-peryleneiimide have been designed and synthesized. The dual-switching behaviors of the sensors were based on the structural transformations of rhodamine and an intramolecular photoinduced electron transfer (PET) process from rhodamine to perylenediimide. These probes exhibited excellent sensitivity to protons with enhanced fluorescence emission from 500 nm to 580 nm. The fluorescence changes of probes were reversible within a wide range of pH values from 2.0 to 11.0. Moreover, the sensors exhibited high selectivity, short response time, and long lifetime toward protons. The possible mechanism was investigated by the DFT calculation and 1H NMR. According to the experiment of confocal laser scanning microscopy, these probes could be used to detect the acidic pH variations in living cells.

The dual-switching behaviors of the sensors were based on the structural transformations of rhodamine and an intramolecular photoinduced electron transfer process. The probes exhibited excellent sensitivity to protons with enhanced fluorescence emission from 500 nm to 580 nm.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 27, Issue 6, June 2016, Pages 879–886
نویسندگان
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