کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1254433 | 971375 | 2012 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A facile and one-pot electrochemical method for the synthesis of a new anthraquinonethioether
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The reaction of electrochemically generated anthradiquinone as a Michael acceptor with 2-mercaptobenzothiazole and 2-mercaptobenzoxazole, as nucleophiles in ethanol/water mixtures has been studied by means of cyclic voltammetry. Our voltammetric data indicate that produced anthradiquinone participates in Michael addition reaction with nucleophiles and via an ECEC mechanism converts to the new anthraquinonethioether derivatives. Based on an EC mechanism, the observed homogeneous rate constant of the Michael reaction of anthradiquinone with nucleophiles were estimated by comparing the experimental cyclic voltammograms with the digital simulated results.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 23, Issue 5, May 2012, Pages 553–556
Journal: Chinese Chemical Letters - Volume 23, Issue 5, May 2012, Pages 553–556
نویسندگان
Davood Nematollahi, Bayan Moradi, Fahimeh Varmaghani,