کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1254591 | 971381 | 2016 | 6 صفحه PDF | دانلود رایگان |
A new catalyst, Pd particles supported on the N-doped porous carbon (PC) derived from Zn-based metal–organic frameworks (zeolitic imidazolate framework: ZIF-8), was successfully prepared for the first time. The as-prepared catalyst was designated as N-doped PC-Pd, and characterized by X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, scanning electron microscope, N2 adsorption and inductively coupled plasma atomic emission spectroscopy. The N-doped PC-Pd composite exhibited high catalytic activity toward the Suzuki–Miyaura cross-coupling reactions. The yields of the products were in the range of 90%–99%. The catalyst could be readily recycled and reused at least 6 consecutive cycles without a significant loss of its catalytic activity.
An efficient Pd catalyst supported on N-doped porous carbon was developed for the Suzuki–Miyaura coupling reaction for the first time. The prepared catalyst can be readily recovered and reused 6 times without significant loss of catalytic activity.Figure optionsDownload as PowerPoint slide
Journal: Chinese Chemical Letters - Volume 27, Issue 1, January 2016, Pages 149–154