کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1255045 | 971405 | 2010 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Solvent-free preparation of arylaminotetrazole derivatives using aluminum(III) hydrogensulfate as an effective catalyst
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
An efficient and simple method for the preparation of 5-arylamino-1H-tetrazole and 1-aryl-5-amino-1H-tetrazole derivatives is reported using aluminum(III) hydrogensulfate (Al(HSO4)3) as an effective heterogeneous catalyst from secondary arylcyanamides. Generally, when the substitution in arylcyanamide is strongly electron-withdrawing the position of equilibrium would shift toward the isomer of 1-aryl-5-amino-1H-tetrazole (B) and as the electron-donating of substituent increased, the position of equilibrium is shifted toward the isomer of 5-arylamino-1H-tetrazole (A). The present methodology offers several advantages, such as excellent yields, short reaction times, easy work-up and greener conditions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 21, Issue 8, August 2010, Pages 892–896
Journal: Chinese Chemical Letters - Volume 21, Issue 8, August 2010, Pages 892–896
نویسندگان
Ferydoon Khamooshi, Ali Reza Modarresi-Alam,