کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1257973 | 971590 | 2010 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Spectrophotometric determination of acidity constants of 4-(2′–thiazolylazo)- resorcinol (TAR) in water–organic mixtures
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Spectrophotometric determination of acidity constants of 4-(2′–thiazolylazo)- resorcinol (TAR) in water–organic mixtures Spectrophotometric determination of acidity constants of 4-(2′–thiazolylazo)- resorcinol (TAR) in water–organic mixtures](/preview/png/1257973.png)
چکیده انگلیسی
The acidity constants of TAR in different water–organic solvent binary mixtures at 25 °C have been determined spectrophotometrically. DATa ANalysis (DATAN) program was used for calculations of the acidity constants and pure spectra of all formed species and their concentration distribution diagram in applied pH interval. Results show that there are a fairly inverse relationship between acidity constants and the mole fraction of the organic solvent in the binary mixtures. Effects of solvent composition on the pKas and pure spectrum of each component are also discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 21, Issue 6, June 2010, Pages 725–729
Journal: Chinese Chemical Letters - Volume 21, Issue 6, June 2010, Pages 725–729
نویسندگان
Ali Benvidi, Fatemeh Heidari, M. Mazloum Ardakani, Ali Mohammad Hajishabani, Jahanbakhsh Ghasemi,