کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1258222 | 971607 | 2016 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Luminescent polymer electrolytes based on chitosan and containing europium triflate Luminescent polymer electrolytes based on chitosan and containing europium triflate](/preview/png/1258222.png)
Solid polymer electrolytes based on chitosan and europium triflate were prepared by solvent casting and characterized by X-ray diffraction, scanning electron microscopy (SEM), atomic force microscopy (AFM), and photoluminescence spectroscopy. The X-ray diffraction exhibited that the samples were essentially amorphous with organized regions over the whole range of the salt content studied. The AFM analysis demonstrated that the smoother sample had roughness of 4.39 nm. Surface visualization through SEM revealed good homogeneity without any phase separation for more conductive samples and the less conductive showed some imperfections on the surface. The emission and excitation spectra displayed the characteristic bands of Eu(CF3SO3)3 in addition to broad bands corresponding to the polymer host. The excited state 5D0 lifetime values ranged from 0.29–0.37 ms for the studied samples.
Graphical AbstractThis paper describes structural, electrical and microscopically studies of the chitosan-europium triflate luminescent biomembranes as promising candidates to be applied in electroluminescent devicesFigure optionsDownload as PowerPoint slide
Journal: Journal of Rare Earths - Volume 34, Issue 7, July 2016, Pages 661–666