کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1258520 | 971622 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Photopromoted methoxycarbonylation of olefin with methyl formate by Co(OAc)2
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Photopromoted methoxycarbonylation of olefin with methyl formate by Co(OAc)2 Photopromoted methoxycarbonylation of olefin with methyl formate by Co(OAc)2](/preview/png/1258520.png)
چکیده انگلیسی
The photopromoted methoxycarbonylation of olefin with methyl formate catalyzed by Co(OAc)2 at ambient conditions has been carried out. The results indicated that the reaction activity increased with the increasing temperature. Methyl formate decomposed into CO and CH3OH firstly under irradiation, and then the methoxycarbonylation of olefin proceeded under catalysis of Co(OAc)2. The mechanism of methyl formate participating in the methoxycarbonylation is verified by the IR analysis and the labeling experiments of CD3OD and CH318OH.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chinese Chemical Letters - Volume 18, Issue 1, January 2007, Pages 17–20
Journal: Chinese Chemical Letters - Volume 18, Issue 1, January 2007, Pages 17–20
نویسندگان
Ying Na Cui, Jing Mei Yin, Da Bin Gao, Ying Ping Jia, Guang Yun Zhou, Shen Min Li,