کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1265999 | 1496878 | 2015 | 8 صفحه PDF | دانلود رایگان |
• Sonochemical method is used to prepare high voltage spinel LiNi0.5Mn1.5O4.
• Sonochemistry has been proven to be green and cost-effective method.
• The ICP results of the molar ratios of Li:Ni:Mn are close to 2:1:3.
• LiNi0.5Mn1.5O4 is a promising cathode material for high voltage Li-ion batteries.
• Addition of glucose helps to enhance crystallinity and electrochemical activity.
LiNi0.5Mn1.5O4 was synthesized as a cathode material for Li-ion batteries by a sonochemical reaction followed by annealing, and was characterized by XRD, SEM, HRTEM and Raman spectroscopy in conjunction with electrochemical measurements. Two samples were prepared by a sonochemical process, one without using glucose (sample-S1) and another with glucose (sample-S2). An initial discharge specific capacity of 130 mA h g−1 is obtained for LiNi0.5Mn1.5O4 at a relatively slow rate of C/10 in galvanostatic charge–discharge cycling. The capacity retention upon 50 cycles at this rate was around 95.4% and 98.9% for sample-S1 and sample-S2, respectively, at 30 °C.
Journal: Ultrasonics Sonochemistry - Volume 26, September 2015, Pages 332–339