کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1267574 972360 2011 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electronic properties associated with conformational changes in azobenzene-derivative molecular junctions
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Electronic properties associated with conformational changes in azobenzene-derivative molecular junctions
چکیده انگلیسی

The electronic properties of azobenzene-derivative ([4-(phenylazo)phenoxy]hexane-1-thiol) molecular junctions were studied in terms of their molecular configurations with vertical device structure as solid-state device platform. This molecule has two distinct molecular configurations (trans- and cis-isomer) depending on the wavelength of irradiating light, which converts from more thermodynamically stable trans-isomer to cis-isomer under UV exposure (∼365 nm) and reversible photoisomerization of cis-isomer to trans-isomer under visible light (400–500 nm). The two states showed that the conductance of cis-isomer (compact form) was higher than that of trans-isomer (extended form). From the temperature-variable electrical characterization, the main charge conduction mechanism for the two isomers was found to be tunneling. And, from the transition voltage spectroscopy analysis and ultraviolet photoelectron spectroscopy measurement, the origin of such result can be explained by reduction of molecular tunneling distance between two isomers.

Figure optionsDownload as PowerPoint slideHighlights
► Electronic properties of azobenzene-derivative molecular junctions.
► Photoisomerization between trans-isomer and cis-isomer.
► Conductance of cis-isomer is higher than that of trans-isomer.
► Conduction mechanism for the isomers is tunneling.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Organic Electronics - Volume 12, Issue 12, December 2011, Pages 2144–2150
نویسندگان
, , , , , , , , ,