کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1283995 1497960 2014 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemical properties of Li7La3Zr2O12-based solid state battery
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Electrochemical properties of Li7La3Zr2O12-based solid state battery
چکیده انگلیسی


• All-solid-state battery is studied using LLZ ceramics.
• The cell structure is LiFePO4/Li7La3Zr2O12(electrolyte)/Li metal.
• The electrochemical performance is dependent on the conductivity of LLZ.
• The secondary phase is formed at grain boundary by the reaction of moisture and La.
• The secondary phase affects the conductivity of LLZ.

The effect of moisture on the Li ion conduction of Li7La3Zr2O12 (LLZ) ceramic and the electrochemical properties of LLZ-based solid state battery was investigated using LiFePO4 (LFP) film as a cathode. LFP film was fabricated by aerosol deposition method. The secondary phase was formed in LLZ ceramic, when the specimen was exposed in humid air. With the formation of the secondary phase, the severe degradation of Li ion conduction was observed at the grain boundary. In addition, the charge and discharge capacities of LLZ-based solid state cell were quite low at room temperature, although, at 140 °C, the cell showed the high capacity. Therefore, the protection of LLZ ceramic from moisture might be required to gain the high capacity of LLZ-based solid state cell at room temperature.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 272, 25 December 2014, Pages 554–558
نویسندگان
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