An opposite change rule in carbon nanotubes supported platinum catalyst for methanol oxidation and oxygen reduction reactions

• A series of carbon nanotubes supported Pt (Pt/CNTs) with same size of Pt are prepared.
• Oxygen reduction (ORR) and methanol oxidation (MOR) reactions are studied contrastively.
• Pt/CNTs show an opposite change rule for ORR and MOR along the different Pt loadings.
• The proton transfer is the key factor to determine the MOR activity.
• The reasons for the intrinsic difference between for ORR and MOR are revealed.

The electrocatalytic performances of carbon nanotubes supported platinum (Pt/CNTs) with different Pt loadings for oxygen reduction reaction (ORR) and methanol oxidation (MOR) are studied contrastively. Pt/CNTs showed an opposite change rule along different Pt loadings for ORR and MOR, which is discussed based on the charge transportation and mass transfer. The results show that at low Pt loading, proton conduction is the key factor, which determines the MOR activity; at high Pt loading, mass transfer is crucial, which decides the ORR activity of Pt/CNT catalysts. The viewpoint proposed in this paper can guide the design and preparation of Pt based catalysts for the commercialization of direct methanol fuel cells.

An opposite change rule along different Pt loadings in Pt/CNTs for oxygen reduction reaction (ORR) and methanol oxidation (MOR) was revealed based on the charge transportation and mass transfer characters.Figure optionsDownload as PowerPoint slide