کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1284733 973084 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Crystal structure and physical properties of lithium difluoro(oxalato)borate (LiDFOB or LiBF2Ox)
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Crystal structure and physical properties of lithium difluoro(oxalato)borate (LiDFOB or LiBF2Ox)
چکیده انگلیسی

The structural characterization and properties of lithium difluoro(oxalato)borate (LiDFOB) are reported. LiDFOB was synthesized as previously described in the literature via direct reaction of boron trifluoride diethyl etherate with lithium oxalate. The crystal structure of the salt was determined from single crystal X-ray diffraction yielding a highly symmetric orthorhombic structure (Cmcm, a = 6.2623(8) Å, b = 11.4366(14) Å, c = 6.3002(7) Å, V = 451.22(9) Å3, Z = 4 at 110 K). Single crystal X-ray diffraction of a dihydrate of LiDFOB yielded a monoclinic structure (P21/c, a = 9.5580(3) Å, b = 12.7162(4) Å, c = 5.4387(2) Å, V = 634.63(4) Å3, Z = 4 at 110 K). Along with the crystal structures, additional structural information and the properties of LiDFOB (via 11B and 19F NMR, DSC, TGA and Raman spectroscopy) have been compared with those of LiBF4 and LiBOB to better understand the differences between these lithium battery electrolyte salts.


► Crystal structures reported for LiDFOB and its dihydrate.
► Raman spectra of LiDFOB contrasted with LiBF4 and LiBOB.
► DSC and TGA indicate that vapor pressure plays significant role in LiDFOB thermal decomposition.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 196, Issue 22, 15 November 2011, Pages 9737–9742
نویسندگان
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