کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1284832 | 973094 | 2011 | 5 صفحه PDF | دانلود رایگان |
NH4V3O8·0.2H2O is synthesized by sodium dodecyl sulfonate (SDS) assisted hydrothermal method and its electrochemical performance is investigated. The as-prepared material is characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), infrared (IR) spectrum, differential scanning calorimetry and thermal gravimetry (DSC/TG), cyclic voltammetry (CV), and charge–discharge cycling test. The results show a pure NH4V3O8·0.2H2O phase with flake-like morphology is obtained and the average flake thickness is about 150 nm. The NH4V3O8·0.2H2O electrode has a good lithium ion insertion/extraction ability with the highest discharge capacity of 225.9 mAh g−1 during 1.8–4.0 V versus Li at the constant current density of 15 mA g−1. After 30 cycles, it still maintains a high discharge capacity of 209.4 mAh g−1, demonstrating good cyclic stability. Interestingly, at the discharge process a new (NH4)LixV3O8·0.2H2O compound is formed due to the new lithium ion from lithium metal anode.
Journal: Journal of Power Sources - Volume 196, Issue 2, 15 January 2011, Pages 788–792