کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1285659 | 1497928 | 2016 | 8 صفحه PDF | دانلود رایگان |
• A series of NF-based composites were synthesized in situ on nickel foam.
• The composites were directly used as binder-free electrodes for Li-ion batteries.
• The composite electrodes were first designed and fabricated for Li-ion batteries.
• The composite electrodes were prepared by a simple one-step hydrothermal process.
• The NRNN composite electrode exhibited a high reversible capacity.
A series of nickel foam (NF)-based composites of MxOy/RGO/Ni(OH)2 [MxOy = Co3O4, MnO2, and Ni(OH)2] with diverse multilayer nano-architectures were designed and grown in situ on NF through a one-pot hydrothermal process. Based on the redox reaction between the active NF substrate and graphene oxide (GO), along with electrostatic forces between the Mn+ ions and GO in the solution, strong interactions take place at the interfaces of MxOy/RGO, RGO/Ni(OH)2, and Ni(OH)2/Ni, and thus, there is good contact for electron transfer. These MxOy/RGO/Ni(OH)2 samples were directly used as conductive-agent- and binder-free anodes for lithium ion batteries (LIBs), and the Ni(OH)2/RGO/Ni(OH)2/NF composite electrode showed a high specific capacity, good rate capability, and excellent cycling stability, especially, it had a high reversible capacity of about 1330 mAh g−1 even after 200 cycles at 100 mA g−1. This general strategy presents a promising route for the design and synthesis of various multilayer nano-architectural transition metal oxides (hydroxide)/RGO composites on NF as energy storage materials.
A series of NF-based composites of MxOy/RGO/Ni(OH)2 [MxOy = Co3O4, MnO2, and Ni(OH)2] with diverse multilayer nano-architectures were designed and grown in-situ on nickel foam (NF) through a facile one-pot hydrothermal approach. These composites were directly used as conductive-agent- and binder-free anodes for LIBs, and the Ni(OH)2/RGO/Ni(OH)2/NF composite electrode exhibited a particularly high reversible capacity of about 1330 mAh g−1, even after 200 cycles at 100 mA g−1Figure optionsDownload as PowerPoint slide
Journal: Journal of Power Sources - Volume 304, 1 February 2016, Pages 311–318