کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
1285728 1497929 2016 7 صفحه PDF سفارش دهید دانلود رایگان
عنوان انگلیسی مقاله ISI
Carbon-resistant Ni-Zr0.92Y0.08O2-δ supported solid oxide fuel cells using Ni-Cu-Fe alloy cermet as on-cell reforming catalyst and mixed methane-steam as fuel
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موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Carbon-resistant Ni-Zr0.92Y0.08O2-δ supported solid oxide fuel cells using Ni-Cu-Fe alloy cermet as on-cell reforming catalyst and mixed methane-steam as fuel
چکیده انگلیسی


• The NCF-BZCYYb possesses higher activity for CH4 steam reforming compared to Ni-YSZ.
• The use of NCF-BZCYYb catalyst in the Ni-YSZ supported SOFC is studied.
• NCF-BZCYYb coated single cell exhibits higher electrochemical performance in CH4.
• NCF-BZCYYb coated single cell exhibits better durability and carbon resistance.

Two types of anode-supported cell are fabricated by tape casting, screen printing and sintering processes. The first one is a conventional anode supported cell (ASC); and the other, namely CASC, contains an extra layer of Ni-Cu/Ni-Fe alloys-BaZr0.1Ce0.7Y0.1Yb0.1O3-δ (NCF-BZCYYb) cermet catalyst on the surface of the anode-support. Using CH4-3 mol. % H2O as the fuel, the initial performance of the CASC is moderately improved, compared with that of the ASC; the power density of the CASC and ASC at 500 mA cm−2 and 800 °C remain stable on the level of 470 mW cm−2 for approximately 11 and 0.8 h, respectively, before cell disintegration caused by carbon formation. The performances of the CASC in the fuel of CH4-33.3 mol. % H2O are significantly increased above the level of the ASC, demonstrating an initial peak power density ranging from 280 to 1638 mW cm−2 at temperatures between 600 and 800 °C and a stable power density of 485 mW cm−2 at 500 mA cm−2 and 800 °C for 48 h. Carbon deposition in the anode region of the tested CASC cell is not detected, as the NCF-BZCYYb is a more active catalyst than the Ni-Zr0.92Y0.08O2-δ (YSZ) anode-support for CH4 steam reforming.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 303, 30 January 2016, Pages 340–346
نویسندگان
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